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Photooxidation

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Photooxidation is oxidation brought about by light. Oxidation can involve a chemical species losing electrons; it does not always mean that oxygen is added to a substance. In photooxidation, light induces the oxidation reaction .1

One route begins when a chemical species absorbs light and becomes electronically excited, meaning that its electrons occupy a higher-energy state. The excited species can then lose one or more electrons. Another common route involves a substance reacting with oxygen under the influence of light .1

When oxygen remains incorporated in the product of that second route, the process is also called photooxygenation. The terms therefore overlap, but photooxygenation describes a more specific outcome. Photooxidation therefore does not name a single reaction with one set of products .1

References

  1. International Union of Pure and Applied Chemistry Photooxidation. IUPAC Compendium of Chemical Terminology. 5th edition. 2025. DOI

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